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Carbonylative N-Heterocyclization via Nitrogen-Directed C–C Bond Activation of Nonactivated Cyclopropanes

[Image: see text] Under Rh-catalyzed conditions, secondary amines and anilines function as directing groups to facilitate regioselective C–C bond activation of nonactivated cyclopropanes. The resulting amino-stabilized rhodacycles undergo carbonylative C–N bond formation en route to challenging seve...

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Detalles Bibliográficos
Autores principales: Calow, Adam D. J., Dailler, David, Bower, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9248011/
https://www.ncbi.nlm.nih.gov/pubmed/35715228
http://dx.doi.org/10.1021/jacs.2c02921