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Time-Resolved Infrared Spectroscopy Reveals the pH-Independence of the First Electron Transfer Step in the [FeFe] Hydrogenase Catalytic Cycle

[Image: see text] [FeFe] hydrogenases are highly active catalysts for hydrogen conversion. Their active site has two components: a [4Fe−4S] electron relay covalently attached to the H(2) binding site and a diiron cluster ligated by CO, CN(–), and 2-azapropane-1,3-dithiolate (ADT) ligands. Reduction...

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Detalles Bibliográficos
Autores principales:	Sanchez, Monica L. K., Wiley, Seth, Reijerse, Edward, Lubitz, Wolfgang, Birrell, James A., Dyer, R. Brian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9251755/ https://www.ncbi.nlm.nih.gov/pubmed/35736652 http://dx.doi.org/10.1021/acs.jpclett.2c01467

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