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Semiconductive 2D arrays of pancake-bonded oligomers of partially charged TCNQ radicals
Multicentre two-electron (mc/2e or ‘pancake bonding’) bonding between 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anions was studied on its 14 novel salts with planar organic cations. The formal charges of the TCNQ(δ−) moieties are −1/2 and −2/3, and they form mc/2e bonded dimers, trimers and...
Autores principales: | Molčanov, Krešimir, Milašinović, Valentina, Kojić-Prodić, Biserka, Maltar-Strmečki, Nadica, You, Jiangyang, Šantić, Ana, Kanižaj, Lidija, Stilinović, Vladimir, Fotović, Luka |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9252159/ https://www.ncbi.nlm.nih.gov/pubmed/35844480 http://dx.doi.org/10.1107/S2052252522004717 |
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