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Frequent flaws encountered in the manuscripts of kinetic papers
In the manuscripts dealing with thermoanalytical kinetics, many flaws, mistakes, and misconceptions are encountered repeatedly. In this paper, frequent flaws encountered in manuscript of kinetic papers are reviewed, mainly those originating in the false interpretation of the general rate equation, i...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer International Publishing
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9252552/ https://www.ncbi.nlm.nih.gov/pubmed/35813001 http://dx.doi.org/10.1007/s10973-022-11436-y |
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author | Šimon, Peter Dubaj, Tibor Cibulková, Zuzana |
author_facet | Šimon, Peter Dubaj, Tibor Cibulková, Zuzana |
author_sort | Šimon, Peter |
collection | PubMed |
description | In the manuscripts dealing with thermoanalytical kinetics, many flaws, mistakes, and misconceptions are encountered repeatedly. In this paper, frequent flaws encountered in manuscript of kinetic papers are reviewed, mainly those originating in the false interpretation of the general rate equation, improper employment of integral isoconversional methods, conclusions drawn from the values of a single kinetic parameter, absence of error estimation and application of single-heating rate methods. Assessment of the quality of kinetic treatment is also noticed. Some experimental imperfections that could lead to incorrect values of kinetic parameters are mentioned. |
format | Online Article Text |
id | pubmed-9252552 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | Springer International Publishing |
record_format | MEDLINE/PubMed |
spelling | pubmed-92525522022-07-05 Frequent flaws encountered in the manuscripts of kinetic papers Šimon, Peter Dubaj, Tibor Cibulková, Zuzana J Therm Anal Calorim Article In the manuscripts dealing with thermoanalytical kinetics, many flaws, mistakes, and misconceptions are encountered repeatedly. In this paper, frequent flaws encountered in manuscript of kinetic papers are reviewed, mainly those originating in the false interpretation of the general rate equation, improper employment of integral isoconversional methods, conclusions drawn from the values of a single kinetic parameter, absence of error estimation and application of single-heating rate methods. Assessment of the quality of kinetic treatment is also noticed. Some experimental imperfections that could lead to incorrect values of kinetic parameters are mentioned. Springer International Publishing 2022-07-04 2022 /pmc/articles/PMC9252552/ /pubmed/35813001 http://dx.doi.org/10.1007/s10973-022-11436-y Text en © Akadémiai Kiadó, Budapest, Hungary 2022 This article is made available via the PMC Open Access Subset for unrestricted research re-use and secondary analysis in any form or by any means with acknowledgement of the original source. These permissions are granted for the duration of the World Health Organization (WHO) declaration of COVID-19 as a global pandemic. |
spellingShingle | Article Šimon, Peter Dubaj, Tibor Cibulková, Zuzana Frequent flaws encountered in the manuscripts of kinetic papers |
title | Frequent flaws encountered in the manuscripts of kinetic papers |
title_full | Frequent flaws encountered in the manuscripts of kinetic papers |
title_fullStr | Frequent flaws encountered in the manuscripts of kinetic papers |
title_full_unstemmed | Frequent flaws encountered in the manuscripts of kinetic papers |
title_short | Frequent flaws encountered in the manuscripts of kinetic papers |
title_sort | frequent flaws encountered in the manuscripts of kinetic papers |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9252552/ https://www.ncbi.nlm.nih.gov/pubmed/35813001 http://dx.doi.org/10.1007/s10973-022-11436-y |
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