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The underappreciated influence of ancillary halide on metal–ligand proton tautomerism
Syntheses of Vaska-type complexes [IrP(2)X(CO)] (P = phosphine, X = halide) with all four common halides (fluoride, chloride, bromide, and iodide) was attempted using a protic and hemilabile imidazolyl di-tert-butyl phosphine ligand. In the solid-state, all four complexes were found to be ionic with...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9258501/ https://www.ncbi.nlm.nih.gov/pubmed/35865898 http://dx.doi.org/10.1039/d2sc00279e |