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Synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-N-phenyl-N′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class

The title compound {systematic name: rac-2-[7-methyl-4-(4-methylphenyl)-4-(phenylimino)-6,6-bis(propan-2-yl)-3-oxa-4λ(6)-thia-5-aza-6-silaoct-4-en-1-yl]-2,3-dihydro-1H-isoindole-1,3-dione}, C(32)H(41)N(3)O(3)SSi, was synthesized by desoxychlorination of 4-methyl-N-phenyl-N′-(triisopropyl­sil­yl)benz...

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Autores principales: Friedrich, Erik, Heinrich, Timo, Rosenberger, Lara, Krier, Mireille, Marek, Stephanie, Reggelin, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260357/
https://www.ncbi.nlm.nih.gov/pubmed/35855363
http://dx.doi.org/10.1107/S2056989022005904
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author Friedrich, Erik
Heinrich, Timo
Rosenberger, Lara
Krier, Mireille
Marek, Stephanie
Reggelin, Michael
author_facet Friedrich, Erik
Heinrich, Timo
Rosenberger, Lara
Krier, Mireille
Marek, Stephanie
Reggelin, Michael
author_sort Friedrich, Erik
collection PubMed
description The title compound {systematic name: rac-2-[7-methyl-4-(4-methylphenyl)-4-(phenylimino)-6,6-bis(propan-2-yl)-3-oxa-4λ(6)-thia-5-aza-6-silaoct-4-en-1-yl]-2,3-dihydro-1H-isoindole-1,3-dione}, C(32)H(41)N(3)O(3)SSi, was synthesized by desoxychlorination of 4-methyl-N-phenyl-N′-(triisopropyl­sil­yl)benzene­sul­fon­imid­am­ide and subsequent reaction with 2-(2-hy­droxy­eth­yl)isoindoline-1,3-dione. The racemic compound was crystallized from isopropanol. The structural characterization by single-crystal X-ray diffraction revealed two double-bonded nitro­gen atoms to the central sulfur atom and an overall crystal packing driven by its aromatic inter­actions.
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spelling pubmed-92603572022-07-18 Synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-N-phenyl-N′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class Friedrich, Erik Heinrich, Timo Rosenberger, Lara Krier, Mireille Marek, Stephanie Reggelin, Michael Acta Crystallogr E Crystallogr Commun Research Communications The title compound {systematic name: rac-2-[7-methyl-4-(4-methylphenyl)-4-(phenylimino)-6,6-bis(propan-2-yl)-3-oxa-4λ(6)-thia-5-aza-6-silaoct-4-en-1-yl]-2,3-dihydro-1H-isoindole-1,3-dione}, C(32)H(41)N(3)O(3)SSi, was synthesized by desoxychlorination of 4-methyl-N-phenyl-N′-(triisopropyl­sil­yl)benzene­sul­fon­imid­am­ide and subsequent reaction with 2-(2-hy­droxy­eth­yl)isoindoline-1,3-dione. The racemic compound was crystallized from isopropanol. The structural characterization by single-crystal X-ray diffraction revealed two double-bonded nitro­gen atoms to the central sulfur atom and an overall crystal packing driven by its aromatic inter­actions. International Union of Crystallography 2022-06-10 /pmc/articles/PMC9260357/ /pubmed/35855363 http://dx.doi.org/10.1107/S2056989022005904 Text en © Friedrich et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Friedrich, Erik
Heinrich, Timo
Rosenberger, Lara
Krier, Mireille
Marek, Stephanie
Reggelin, Michael
Synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-N-phenyl-N′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class
title Synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-N-phenyl-N′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class
title_full Synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-N-phenyl-N′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class
title_fullStr Synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-N-phenyl-N′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class
title_full_unstemmed Synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-N-phenyl-N′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class
title_short Synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-N-phenyl-N′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class
title_sort synthesis and crystal structure of rac-2-(1,3-dioxo­isoindolin-2-yl)ethyl 4-methyl-n-phenyl-n′-(tri­iso­propyl­sil­yl)benzene­sulfondiimidoate: the first member of a new substance class
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260357/
https://www.ncbi.nlm.nih.gov/pubmed/35855363
http://dx.doi.org/10.1107/S2056989022005904
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