Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide

In the title mol­ecule, C(9)H(10)ClNO(2), the meth­oxy group lies very close to the plane of the phenyl ring while the acetamido group is twisted out of this plane by 28.87 (5)°. In the crystal, a three-dimensional structure is generated by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds plus C—H⋯π(ring) int...

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Detalles Bibliográficos
Autores principales: Missioui, Mohcine, Guerrab, Walid, Nchioua, Intissar, El Moutaouakil Ala Allah, Abderrazzak, Kalonji Mubengayi, Camille, Alsubari, Abdulsalam, Mague, Joel T., Ramli, Youssef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260361/
https://www.ncbi.nlm.nih.gov/pubmed/35855360
http://dx.doi.org/10.1107/S205698902200576X
Descripción
Sumario:In the title mol­ecule, C(9)H(10)ClNO(2), the meth­oxy group lies very close to the plane of the phenyl ring while the acetamido group is twisted out of this plane by 28.87 (5)°. In the crystal, a three-dimensional structure is generated by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds plus C—H⋯π(ring) inter­actions. A Hirshfeld surface analysis of the inter­molecular inter­actions was performed and indicated that C⋯H/H⋯C inter­actions make the largest contribution to the surface area (33.4%).

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