Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide

In the title mol­ecule, C(9)H(10)ClNO(2), the meth­oxy group lies very close to the plane of the phenyl ring while the acetamido group is twisted out of this plane by 28.87 (5)°. In the crystal, a three-dimensional structure is generated by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds plus C—H⋯π(ring) int...

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Autores principales: Missioui, Mohcine, Guerrab, Walid, Nchioua, Intissar, El Moutaouakil Ala Allah, Abderrazzak, Kalonji Mubengayi, Camille, Alsubari, Abdulsalam, Mague, Joel T., Ramli, Youssef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260361/
https://www.ncbi.nlm.nih.gov/pubmed/35855360
http://dx.doi.org/10.1107/S205698902200576X
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author Missioui, Mohcine
Guerrab, Walid
Nchioua, Intissar
El Moutaouakil Ala Allah, Abderrazzak
Kalonji Mubengayi, Camille
Alsubari, Abdulsalam
Mague, Joel T.
Ramli, Youssef
author_facet Missioui, Mohcine
Guerrab, Walid
Nchioua, Intissar
El Moutaouakil Ala Allah, Abderrazzak
Kalonji Mubengayi, Camille
Alsubari, Abdulsalam
Mague, Joel T.
Ramli, Youssef
author_sort Missioui, Mohcine
collection PubMed
description In the title mol­ecule, C(9)H(10)ClNO(2), the meth­oxy group lies very close to the plane of the phenyl ring while the acetamido group is twisted out of this plane by 28.87 (5)°. In the crystal, a three-dimensional structure is generated by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds plus C—H⋯π(ring) inter­actions. A Hirshfeld surface analysis of the inter­molecular inter­actions was performed and indicated that C⋯H/H⋯C inter­actions make the largest contribution to the surface area (33.4%).
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spelling pubmed-92603612022-07-18 Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide Missioui, Mohcine Guerrab, Walid Nchioua, Intissar El Moutaouakil Ala Allah, Abderrazzak Kalonji Mubengayi, Camille Alsubari, Abdulsalam Mague, Joel T. Ramli, Youssef Acta Crystallogr E Crystallogr Commun Research Communications In the title mol­ecule, C(9)H(10)ClNO(2), the meth­oxy group lies very close to the plane of the phenyl ring while the acetamido group is twisted out of this plane by 28.87 (5)°. In the crystal, a three-dimensional structure is generated by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds plus C—H⋯π(ring) inter­actions. A Hirshfeld surface analysis of the inter­molecular inter­actions was performed and indicated that C⋯H/H⋯C inter­actions make the largest contribution to the surface area (33.4%). International Union of Crystallography 2022-06-07 /pmc/articles/PMC9260361/ /pubmed/35855360 http://dx.doi.org/10.1107/S205698902200576X Text en © Missioui et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Missioui, Mohcine
Guerrab, Walid
Nchioua, Intissar
El Moutaouakil Ala Allah, Abderrazzak
Kalonji Mubengayi, Camille
Alsubari, Abdulsalam
Mague, Joel T.
Ramli, Youssef
Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide
title Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide
title_full Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide
title_fullStr Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide
title_short Crystal structure and Hirshfeld surface analysis of 2-chloro-N-(4-meth­oxy­phen­yl)acetamide
title_sort crystal structure and hirshfeld surface analysis of 2-chloro-n-(4-meth­oxy­phen­yl)acetamide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260361/
https://www.ncbi.nlm.nih.gov/pubmed/35855360
http://dx.doi.org/10.1107/S205698902200576X
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