Crystal structure and Hirshfeld surface analysis of 2,2′-(phenyl­aza­nedi­yl)bis­(1-phenyl­ethan-1-one)

The whole mol­ecule of the title compound, C(22)H(19)NO(2), is generated by twofold rotational symmetry. The N atom exhibits a trigonal-planar geometry and is located on the twofold rotation axis. In the crystal, mol­ecules are linked by C—H⋯O contacts with R (2) (2)(12) ring motifs, and C—H⋯π inter...

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Detalles Bibliográficos
Autores principales: Naghiyev, Farid N., Khrustalev, Victor N., Safronenko, Marina G., Akkurt, Mehmet, Khalilov, Ali N., Bhattarai, Ajaya, Mamedov, İbrahim G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260364/
https://www.ncbi.nlm.nih.gov/pubmed/35855356
http://dx.doi.org/10.1107/S2056989022005382
Descripción
Sumario:The whole mol­ecule of the title compound, C(22)H(19)NO(2), is generated by twofold rotational symmetry. The N atom exhibits a trigonal-planar geometry and is located on the twofold rotation axis. In the crystal, mol­ecules are linked by C—H⋯O contacts with R (2) (2)(12) ring motifs, and C—H⋯π inter­actions, resulting in ribbons along the c-axis direction. van der Waals inter­actions between these ribbons consolidate the mol­ecular packing. Hirshfeld surface analysis indicates that the greatest contributions to the crystal packing are from H⋯H (45.5%), C⋯H/H⋯C (38.2%) and O⋯H/H⋯O (16.0%) inter­actions.

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