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Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one)
The whole molecule of the title compound, C(22)H(19)NO(2), is generated by twofold rotational symmetry. The N atom exhibits a trigonal-planar geometry and is located on the twofold rotation axis. In the crystal, molecules are linked by C—H⋯O contacts with R (2) (2)(12) ring motifs, and C—H⋯π inter...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260364/ https://www.ncbi.nlm.nih.gov/pubmed/35855356 http://dx.doi.org/10.1107/S2056989022005382 |
| _version_ | 1784742011497086976 |
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| author | Naghiyev, Farid N. Khrustalev, Victor N. Safronenko, Marina G. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. |
| author_facet | Naghiyev, Farid N. Khrustalev, Victor N. Safronenko, Marina G. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. |
| author_sort | Naghiyev, Farid N. |
| collection | PubMed |
| description | The whole molecule of the title compound, C(22)H(19)NO(2), is generated by twofold rotational symmetry. The N atom exhibits a trigonal-planar geometry and is located on the twofold rotation axis. In the crystal, molecules are linked by C—H⋯O contacts with R (2) (2)(12) ring motifs, and C—H⋯π interactions, resulting in ribbons along the c-axis direction. van der Waals interactions between these ribbons consolidate the molecular packing. Hirshfeld surface analysis indicates that the greatest contributions to the crystal packing are from H⋯H (45.5%), C⋯H/H⋯C (38.2%) and O⋯H/H⋯O (16.0%) interactions. |
| format | Online Article Text |
| id | pubmed-9260364 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-92603642022-07-18 Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one) Naghiyev, Farid N. Khrustalev, Victor N. Safronenko, Marina G. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. Acta Crystallogr E Crystallogr Commun Research Communications The whole molecule of the title compound, C(22)H(19)NO(2), is generated by twofold rotational symmetry. The N atom exhibits a trigonal-planar geometry and is located on the twofold rotation axis. In the crystal, molecules are linked by C—H⋯O contacts with R (2) (2)(12) ring motifs, and C—H⋯π interactions, resulting in ribbons along the c-axis direction. van der Waals interactions between these ribbons consolidate the molecular packing. Hirshfeld surface analysis indicates that the greatest contributions to the crystal packing are from H⋯H (45.5%), C⋯H/H⋯C (38.2%) and O⋯H/H⋯O (16.0%) interactions. International Union of Crystallography 2022-06-07 /pmc/articles/PMC9260364/ /pubmed/35855356 http://dx.doi.org/10.1107/S2056989022005382 Text en © Naghiyev et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Naghiyev, Farid N. Khrustalev, Victor N. Safronenko, Marina G. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one) |
| title | Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one) |
| title_full | Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one) |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one) |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one) |
| title_short | Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one) |
| title_sort | crystal structure and hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260364/ https://www.ncbi.nlm.nih.gov/pubmed/35855356 http://dx.doi.org/10.1107/S2056989022005382 |
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