Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen

[Image: see text] The hydrogen-bonded organic frameworks (HOFs) have gained significant attention due to their various alluring applications in the fascinating field of supramolecular chemistry. Herein, we report the electrocatalytic activity of HOFs toward the hydrogen evolution reaction (HER) by u...

Descripción completa

Detalles Bibliográficos
Autores principales: Giri, Lopamudra, Mohanty, Bishnupad, Thapa, Ranjit, Jena, Bikash Kumar, Pedireddi, Venkateswara Rao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260925/
https://www.ncbi.nlm.nih.gov/pubmed/35811884
http://dx.doi.org/10.1021/acsomega.2c01585
_version_ 1784742151412776960
author Giri, Lopamudra
Mohanty, Bishnupad
Thapa, Ranjit
Jena, Bikash Kumar
Pedireddi, Venkateswara Rao
author_facet Giri, Lopamudra
Mohanty, Bishnupad
Thapa, Ranjit
Jena, Bikash Kumar
Pedireddi, Venkateswara Rao
author_sort Giri, Lopamudra
collection PubMed
description [Image: see text] The hydrogen-bonded organic frameworks (HOFs) have gained significant attention due to their various alluring applications in the fascinating field of supramolecular chemistry. Herein, we report the electrocatalytic activity of HOFs toward the hydrogen evolution reaction (HER) by utilizing the molecular adduct of cyanuric and trithiocyanuric acid with various organic substrates (melamine and 4,4′-bipyridine). Both the experimental and theoretical findings provide insights and validate the electrocatalytic activity toward HER applications. This work contributes significantly to designing novel highly efficient metal-free HOF-based electrocatalysts for the HER.
format Online
Article
Text
id pubmed-9260925
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-92609252022-07-08 Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen Giri, Lopamudra Mohanty, Bishnupad Thapa, Ranjit Jena, Bikash Kumar Pedireddi, Venkateswara Rao ACS Omega [Image: see text] The hydrogen-bonded organic frameworks (HOFs) have gained significant attention due to their various alluring applications in the fascinating field of supramolecular chemistry. Herein, we report the electrocatalytic activity of HOFs toward the hydrogen evolution reaction (HER) by utilizing the molecular adduct of cyanuric and trithiocyanuric acid with various organic substrates (melamine and 4,4′-bipyridine). Both the experimental and theoretical findings provide insights and validate the electrocatalytic activity toward HER applications. This work contributes significantly to designing novel highly efficient metal-free HOF-based electrocatalysts for the HER. American Chemical Society 2022-06-21 /pmc/articles/PMC9260925/ /pubmed/35811884 http://dx.doi.org/10.1021/acsomega.2c01585 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Giri, Lopamudra
Mohanty, Bishnupad
Thapa, Ranjit
Jena, Bikash Kumar
Pedireddi, Venkateswara Rao
Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen
title Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen
title_full Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen
title_fullStr Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen
title_full_unstemmed Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen
title_short Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen
title_sort hydrogen-bonded organic framework structure: a metal-free electrocatalyst for the evolution of hydrogen
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260925/
https://www.ncbi.nlm.nih.gov/pubmed/35811884
http://dx.doi.org/10.1021/acsomega.2c01585
work_keys_str_mv AT girilopamudra hydrogenbondedorganicframeworkstructureametalfreeelectrocatalystfortheevolutionofhydrogen
AT mohantybishnupad hydrogenbondedorganicframeworkstructureametalfreeelectrocatalystfortheevolutionofhydrogen
AT thaparanjit hydrogenbondedorganicframeworkstructureametalfreeelectrocatalystfortheevolutionofhydrogen
AT jenabikashkumar hydrogenbondedorganicframeworkstructureametalfreeelectrocatalystfortheevolutionofhydrogen
AT pedireddivenkateswararao hydrogenbondedorganicframeworkstructureametalfreeelectrocatalystfortheevolutionofhydrogen

Ejemplares similares