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Reaction of Ta(3)(–) Clusters with Molecular Nitrogen: A Mechanism Investigation

[Image: see text] Because of the inertness of molecular nitrogen, its practicable activation under mild conditions is a fundamental challenge. Ta(3)(–) is an exceptionally small cluster that reacts with N(2) at room temperature, leading finally to Ta(3)N(2)(–); Ta(3)N(2)(–) also could react with N(2...

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Detalles Bibliográficos
Autores principales: Sun, Xiaoli, Huang, Xuri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9260930/
https://www.ncbi.nlm.nih.gov/pubmed/35811866
http://dx.doi.org/10.1021/acsomega.2c02138