Contrasting behaviour under pressure reveals the reasons for pyramidalization in tris(amido)uranium(III) and tris(arylthiolate) uranium(III) molecules

A range of reasons has been suggested for why many low-coordinate complexes across the periodic table exhibit a geometry that is bent, rather a higher symmetry that would best separate the ligands. The dominating reason or reasons are still debated. Here we show that two pyramidal UX(3) molecules, i...

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Detalles Bibliográficos
Autores principales: Price, Amy N., Berryman, Victoria, Ochiai, Tatsumi, Shephard, Jacob J., Parsons, Simon, Kaltsoyannis, Nikolas, Arnold, Polly L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9262880/
https://www.ncbi.nlm.nih.gov/pubmed/35798750
http://dx.doi.org/10.1038/s41467-022-31550-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9262880/
https://www.ncbi.nlm.nih.gov/pubmed/35798750
http://dx.doi.org/10.1038/s41467-022-31550-7

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