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Reversible Structural Isomerization of Nature’s Water Oxidation Catalyst Prior to O–O Bond Formation

[Image: see text] Photosynthetic water oxidation is catalyzed by a manganese–calcium oxide cluster, which experiences five “S-states” during a light-driven reaction cycle. The unique “distorted chair”-like geometry of the Mn(4)CaO(5(6)) cluster shows structural flexibility that has been frequently p...

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Detalles Bibliográficos
Autores principales:	Guo, Yu, Messinger, Johannes, Kloo, Lars, Sun, Licheng
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9264352/ https://www.ncbi.nlm.nih.gov/pubmed/35748306 http://dx.doi.org/10.1021/jacs.2c03528

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