The Role of Prussian Blue-Thallium and Potassium Similarities and Differences in Crystal Structures of Selected Cyanido Complexes of W, Fe and Mo

The synthesis and single X-ray crystal structures of Tl(2)[W(CN)(6)(bpy)]·H(2)O, Tl[W(CN)(6)(bpy)], Tl(57)[{Fe(CN)(6)}(12){NO(3)}(9)]·9H(2)O, Tl(4)[W(CN)(8)] and Tl(4)[Mo(CN)(8)] are described. Salts crystalize in the monoclinic or trigonal (Fe) space group. For all complexes, the very unusual “side...

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Autores principales: Hodorowicz, Maciej, Szklarzewicz, Janusz, Jurowska, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9267926/
https://www.ncbi.nlm.nih.gov/pubmed/35806708
http://dx.doi.org/10.3390/ma15134586
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author Hodorowicz, Maciej
Szklarzewicz, Janusz
Jurowska, Anna
author_facet Hodorowicz, Maciej
Szklarzewicz, Janusz
Jurowska, Anna
author_sort Hodorowicz, Maciej
collection PubMed
description The synthesis and single X-ray crystal structures of Tl(2)[W(CN)(6)(bpy)]·H(2)O, Tl[W(CN)(6)(bpy)], Tl(57)[{Fe(CN)(6)}(12){NO(3)}(9)]·9H(2)O, Tl(4)[W(CN)(8)] and Tl(4)[Mo(CN)(8)] are described. Salts crystalize in the monoclinic or trigonal (Fe) space group. For all complexes, the very unusual “side-on” coordination of Tl to C and N of cyanido ligands is observed and compared to potassium cations. The very strong bonding to cyanido ligands with an 8–13 coordination number of thallium is described and discussed. The difference between potassium and thallium bonding is an indication of the biological activity of thallium and the role of Prussian blue in the thallium detoxification procedure.
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spelling pubmed-92679262022-07-09 The Role of Prussian Blue-Thallium and Potassium Similarities and Differences in Crystal Structures of Selected Cyanido Complexes of W, Fe and Mo Hodorowicz, Maciej Szklarzewicz, Janusz Jurowska, Anna Materials (Basel) Article The synthesis and single X-ray crystal structures of Tl(2)[W(CN)(6)(bpy)]·H(2)O, Tl[W(CN)(6)(bpy)], Tl(57)[{Fe(CN)(6)}(12){NO(3)}(9)]·9H(2)O, Tl(4)[W(CN)(8)] and Tl(4)[Mo(CN)(8)] are described. Salts crystalize in the monoclinic or trigonal (Fe) space group. For all complexes, the very unusual “side-on” coordination of Tl to C and N of cyanido ligands is observed and compared to potassium cations. The very strong bonding to cyanido ligands with an 8–13 coordination number of thallium is described and discussed. The difference between potassium and thallium bonding is an indication of the biological activity of thallium and the role of Prussian blue in the thallium detoxification procedure. MDPI 2022-06-29 /pmc/articles/PMC9267926/ /pubmed/35806708 http://dx.doi.org/10.3390/ma15134586 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Hodorowicz, Maciej
Szklarzewicz, Janusz
Jurowska, Anna
The Role of Prussian Blue-Thallium and Potassium Similarities and Differences in Crystal Structures of Selected Cyanido Complexes of W, Fe and Mo
title The Role of Prussian Blue-Thallium and Potassium Similarities and Differences in Crystal Structures of Selected Cyanido Complexes of W, Fe and Mo
title_full The Role of Prussian Blue-Thallium and Potassium Similarities and Differences in Crystal Structures of Selected Cyanido Complexes of W, Fe and Mo
title_fullStr The Role of Prussian Blue-Thallium and Potassium Similarities and Differences in Crystal Structures of Selected Cyanido Complexes of W, Fe and Mo
title_full_unstemmed The Role of Prussian Blue-Thallium and Potassium Similarities and Differences in Crystal Structures of Selected Cyanido Complexes of W, Fe and Mo
title_short The Role of Prussian Blue-Thallium and Potassium Similarities and Differences in Crystal Structures of Selected Cyanido Complexes of W, Fe and Mo
title_sort role of prussian blue-thallium and potassium similarities and differences in crystal structures of selected cyanido complexes of w, fe and mo
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9267926/
https://www.ncbi.nlm.nih.gov/pubmed/35806708
http://dx.doi.org/10.3390/ma15134586
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