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Designed Syntheses of Three {Ni(6)PW(9)}-Based Polyoxometalates, from Isolated Cluster to Cluster-Organic Helical Chain
Three new hexa-Ni-substituted Keggin-type polyoxometalates (POMs), [Ni(6)(OH)(3)- (DACH)(3)(H(2)O)(6)(PW(9)O(34))]·31H(2)O (1), [Ni(DACH)(2)][Ni(6)(OH)(3)(DACH)(3)(HMIP)(2)(H(2)O)(2)(PW(9)O(34))]·56 H(2)O (2), and [Ni(DACH)(2)][Ni(6)(OH)(3)(DACH)(2)(AP)(H(2)O)(5)(PW(9)O(34))]·2H(2)O (3) (DACH = 1,2-...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9268654/ https://www.ncbi.nlm.nih.gov/pubmed/35807541 http://dx.doi.org/10.3390/molecules27134295 |