Simulation of Binodal and Spinodal Curves of Phase State Diagrams for Binary Polymer Systems

A new approach is proposed for simulating binodal and spinodal curves of phase diagrams for binary polymer systems. It is shown that the Flory–Huggins theory makes it possible to predict phase behavior in a wide range of temperatures and concentrations based on limited data on the components’ solubi...

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Autores principales: Chalykh, Anatoly E., Nikulova, Uliana V., Gerasimov, Vladimir K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9268790/
https://www.ncbi.nlm.nih.gov/pubmed/35808572
http://dx.doi.org/10.3390/polym14132524
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author Chalykh, Anatoly E.
Nikulova, Uliana V.
Gerasimov, Vladimir K.
author_facet Chalykh, Anatoly E.
Nikulova, Uliana V.
Gerasimov, Vladimir K.
author_sort Chalykh, Anatoly E.
collection PubMed
description A new approach is proposed for simulating binodal and spinodal curves of phase diagrams for binary polymer systems. It is shown that the Flory–Huggins theory makes it possible to predict phase behavior in a wide range of temperatures and concentrations based on limited data on the components’ solubility. The approbation data of the technique are presented in the example of PS–PB and PS–PMMA systems, for which generalized phase diagrams are constructed.
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spelling pubmed-92687902022-07-09 Simulation of Binodal and Spinodal Curves of Phase State Diagrams for Binary Polymer Systems Chalykh, Anatoly E. Nikulova, Uliana V. Gerasimov, Vladimir K. Polymers (Basel) Article A new approach is proposed for simulating binodal and spinodal curves of phase diagrams for binary polymer systems. It is shown that the Flory–Huggins theory makes it possible to predict phase behavior in a wide range of temperatures and concentrations based on limited data on the components’ solubility. The approbation data of the technique are presented in the example of PS–PB and PS–PMMA systems, for which generalized phase diagrams are constructed. MDPI 2022-06-21 /pmc/articles/PMC9268790/ /pubmed/35808572 http://dx.doi.org/10.3390/polym14132524 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Chalykh, Anatoly E.
Nikulova, Uliana V.
Gerasimov, Vladimir K.
Simulation of Binodal and Spinodal Curves of Phase State Diagrams for Binary Polymer Systems
title Simulation of Binodal and Spinodal Curves of Phase State Diagrams for Binary Polymer Systems
title_full Simulation of Binodal and Spinodal Curves of Phase State Diagrams for Binary Polymer Systems
title_fullStr Simulation of Binodal and Spinodal Curves of Phase State Diagrams for Binary Polymer Systems
title_full_unstemmed Simulation of Binodal and Spinodal Curves of Phase State Diagrams for Binary Polymer Systems
title_short Simulation of Binodal and Spinodal Curves of Phase State Diagrams for Binary Polymer Systems
title_sort simulation of binodal and spinodal curves of phase state diagrams for binary polymer systems
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9268790/
https://www.ncbi.nlm.nih.gov/pubmed/35808572
http://dx.doi.org/10.3390/polym14132524
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