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Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors

Developing high-mobility emissive organic semiconductors with tunable colors is crucial for organic light-emitting transistors (OLETs), a pivotal component of integrated optoelectronic devices, but remains a great challenge. Here, we demonstrate a series of color-tunable, high-mobility, emissive, or...

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Autores principales: Qin, Zhengsheng, Gao, Can, Gao, Haikuo, Wang, Tianyu, Dong, Huanli, Hu, Wenping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9269892/
https://www.ncbi.nlm.nih.gov/pubmed/35857474
http://dx.doi.org/10.1126/sciadv.abp8775
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author Qin, Zhengsheng
Gao, Can
Gao, Haikuo
Wang, Tianyu
Dong, Huanli
Hu, Wenping
author_facet Qin, Zhengsheng
Gao, Can
Gao, Haikuo
Wang, Tianyu
Dong, Huanli
Hu, Wenping
author_sort Qin, Zhengsheng
collection PubMed
description Developing high-mobility emissive organic semiconductors with tunable colors is crucial for organic light-emitting transistors (OLETs), a pivotal component of integrated optoelectronic devices, but remains a great challenge. Here, we demonstrate a series of color-tunable, high-mobility, emissive, organic semiconductors via molecular doping with a high-mobility organic semiconductor, 2,6-diphenylanthracene, as the host. The well-matched molecular structures and sizes with efficient energy transfer between the host and guest enable the intrinsically high charge transport with tunable colors. High mobility with the highest value >2 cm(2) V(−1) s(−1) and strong emission with photoluminescence quantum yield >15.8% are obtained for these molecular-doped organic semiconductors. Last, a large color gamut for constructed OLETs is up to 59% National Television System Committee standard, meanwhile with an extremely high current density approaching 326.4 kA cm(−2), showing great potential for full-color smart display, organic electrically pumped lasers and other related logic circuitries.
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spelling pubmed-92698922022-07-20 Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors Qin, Zhengsheng Gao, Can Gao, Haikuo Wang, Tianyu Dong, Huanli Hu, Wenping Sci Adv Physical and Materials Sciences Developing high-mobility emissive organic semiconductors with tunable colors is crucial for organic light-emitting transistors (OLETs), a pivotal component of integrated optoelectronic devices, but remains a great challenge. Here, we demonstrate a series of color-tunable, high-mobility, emissive, organic semiconductors via molecular doping with a high-mobility organic semiconductor, 2,6-diphenylanthracene, as the host. The well-matched molecular structures and sizes with efficient energy transfer between the host and guest enable the intrinsically high charge transport with tunable colors. High mobility with the highest value >2 cm(2) V(−1) s(−1) and strong emission with photoluminescence quantum yield >15.8% are obtained for these molecular-doped organic semiconductors. Last, a large color gamut for constructed OLETs is up to 59% National Television System Committee standard, meanwhile with an extremely high current density approaching 326.4 kA cm(−2), showing great potential for full-color smart display, organic electrically pumped lasers and other related logic circuitries. American Association for the Advancement of Science 2022-07-08 /pmc/articles/PMC9269892/ /pubmed/35857474 http://dx.doi.org/10.1126/sciadv.abp8775 Text en Copyright © 2022 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). https://creativecommons.org/licenses/by-nc/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (https://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.
spellingShingle Physical and Materials Sciences
Qin, Zhengsheng
Gao, Can
Gao, Haikuo
Wang, Tianyu
Dong, Huanli
Hu, Wenping
Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors
title Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors
title_full Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors
title_fullStr Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors
title_full_unstemmed Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors
title_short Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors
title_sort molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors
topic Physical and Materials Sciences
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9269892/
https://www.ncbi.nlm.nih.gov/pubmed/35857474
http://dx.doi.org/10.1126/sciadv.abp8775
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