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Importance of an Axial Ln(III)–F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues

[Image: see text] The recently reported compound [Dy(III)LF](CF(3)SO(3))(2)·H(2)O (L = 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraaza-cyclododecane) displays a strong axial magnetic anisotropy, due to the short axial Dy–F bond, and single-molecule magnet (SMM) behavior. Following our earlier [...

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Detalles Bibliográficos
Autores principales:	Regincós Martí, Emma, Canaj, Angelos B., Sharma, Tanu, Celmina, Anna, Wilson, Claire, Rajaraman, Gopalan, Murrie, Mark
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9275778/ https://www.ncbi.nlm.nih.gov/pubmed/35727882 http://dx.doi.org/10.1021/acs.inorgchem.2c00556

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