Cargando…
Dinuclear Fluoride Single-Bridged Lanthanoid Complexes as Molecule Magnets: Unprecedented Coupling Constant in a Fluoride-Bridged Gadolinium Compound
[Image: see text] A new synthetic method allows isolating fluoride-bridged complexes Bu(4)N{[M(3NO(2),5Br-H(3)L(1,1,4))](2)(μ-F)} (M = Dy, 1; M = Ho, 2; M = Gd, 3) and Bu(4)N{[Dy(3Br,5Cl-H(3)L(1,2,4))](2)(μ-F)}·2H(2)O, 4·2H(2)O. The crystal structures of 1·5CH(3)C(6)H(5),·2·2H(2)O·0.75THF, 3, and 4·...
| Autores principales: | , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9275779/ https://www.ncbi.nlm.nih.gov/pubmed/35737854 http://dx.doi.org/10.1021/acs.inorgchem.2c00773 |