Rational synthesis of microporous carbons for enhanced post-combustion CO(2) capture via non-hydroxide activation of air carbonised biomass

This work explores the use of a less corrosive activating agent, potassium oxalate (PO), in combination with difficult to activate carbonaceous matter for the preparation of activated carbons. The design of the study allowed a fuller understanding of the workings of PO compared to hydroxide (KOH) activation, and also optimised the preparation of highly microporous carbons with exceptional CO(2) storage capacity under low pressure (≤1 bar) conditions at ambient temperature. The PO activated carbons have a surface area of up to 1760 m(2) g(−1) and are highly microporous with virtually all of the surface area arising from micropores. The porosity of the PO activated carbons can be readily tailored towards having pores of size 6–8 Å, which are highly suited for CO(2) storage at low pressure (i.e., post-combustion capture). At 25 °C, the PO activated carbons can store up to 1.8 and 5.0 mmol g(−1) of CO(2) at 0.15 bar and 1 bar, respectively. On the other hand, KOH activated carbons reach a higher surface area of up to 2700 m(2) g(−1), and store up to 1.0 and 4.0 mmol g(−1) of CO(2). This work demonstrates that PO may be used as a mild, less corrosive and less toxic activating agent for the rational and targeted synthesis of biomass-derived activated carbons with tailored porosity. The targeted synthesis may be aided by careful selection of the biomass starting material as guided by the O/C ratio of the biomass.