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Chiral Iodotriptycenes: Synthesis and Catalytic Applications
New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278095/ https://www.ncbi.nlm.nih.gov/pubmed/35822927 http://dx.doi.org/10.1002/open.202200145 |
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author | Khan, Nasim Itaya, Katsunori Wirth, Thomas |
author_facet | Khan, Nasim Itaya, Katsunori Wirth, Thomas |
author_sort | Khan, Nasim |
collection | PubMed |
description | New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances between the coordinating groups and the iodine moieties in these compounds. |
format | Online Article Text |
id | pubmed-9278095 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-92780952022-07-15 Chiral Iodotriptycenes: Synthesis and Catalytic Applications Khan, Nasim Itaya, Katsunori Wirth, Thomas ChemistryOpen Research Articles New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances between the coordinating groups and the iodine moieties in these compounds. John Wiley and Sons Inc. 2022-07-13 /pmc/articles/PMC9278095/ /pubmed/35822927 http://dx.doi.org/10.1002/open.202200145 Text en © 2022 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Articles Khan, Nasim Itaya, Katsunori Wirth, Thomas Chiral Iodotriptycenes: Synthesis and Catalytic Applications |
title | Chiral Iodotriptycenes: Synthesis and Catalytic Applications |
title_full | Chiral Iodotriptycenes: Synthesis and Catalytic Applications |
title_fullStr | Chiral Iodotriptycenes: Synthesis and Catalytic Applications |
title_full_unstemmed | Chiral Iodotriptycenes: Synthesis and Catalytic Applications |
title_short | Chiral Iodotriptycenes: Synthesis and Catalytic Applications |
title_sort | chiral iodotriptycenes: synthesis and catalytic applications |
topic | Research Articles |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278095/ https://www.ncbi.nlm.nih.gov/pubmed/35822927 http://dx.doi.org/10.1002/open.202200145 |
work_keys_str_mv | AT khannasim chiraliodotriptycenessynthesisandcatalyticapplications AT itayakatsunori chiraliodotriptycenessynthesisandcatalyticapplications AT wirththomas chiraliodotriptycenessynthesisandcatalyticapplications |