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Chiral Iodotriptycenes: Synthesis and Catalytic Applications

New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances...

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Detalles Bibliográficos
Autores principales: Khan, Nasim, Itaya, Katsunori, Wirth, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278095/
https://www.ncbi.nlm.nih.gov/pubmed/35822927
http://dx.doi.org/10.1002/open.202200145
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author Khan, Nasim
Itaya, Katsunori
Wirth, Thomas
author_facet Khan, Nasim
Itaya, Katsunori
Wirth, Thomas
author_sort Khan, Nasim
collection PubMed
description New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances between the coordinating groups and the iodine moieties in these compounds.
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spelling pubmed-92780952022-07-15 Chiral Iodotriptycenes: Synthesis and Catalytic Applications Khan, Nasim Itaya, Katsunori Wirth, Thomas ChemistryOpen Research Articles New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances between the coordinating groups and the iodine moieties in these compounds. John Wiley and Sons Inc. 2022-07-13 /pmc/articles/PMC9278095/ /pubmed/35822927 http://dx.doi.org/10.1002/open.202200145 Text en © 2022 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Khan, Nasim
Itaya, Katsunori
Wirth, Thomas
Chiral Iodotriptycenes: Synthesis and Catalytic Applications
title Chiral Iodotriptycenes: Synthesis and Catalytic Applications
title_full Chiral Iodotriptycenes: Synthesis and Catalytic Applications
title_fullStr Chiral Iodotriptycenes: Synthesis and Catalytic Applications
title_full_unstemmed Chiral Iodotriptycenes: Synthesis and Catalytic Applications
title_short Chiral Iodotriptycenes: Synthesis and Catalytic Applications
title_sort chiral iodotriptycenes: synthesis and catalytic applications
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278095/
https://www.ncbi.nlm.nih.gov/pubmed/35822927
http://dx.doi.org/10.1002/open.202200145
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AT itayakatsunori chiraliodotriptycenessynthesisandcatalyticapplications
AT wirththomas chiraliodotriptycenessynthesisandcatalyticapplications