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Bare and ligand protected planar hexacoordinate silicon in SiSb(3)M(3)(+) (M = Ca, Sr, Ba) clusters

The occurrence of planar hexacoordination is very rare in main group elements. We report here a class of clusters containing a planar hexacoordinate silicon (phSi) atom with the formula SiSb(3)M(3)(+) (M = Ca, Sr, Ba), which have D(3h) ((1)A(1)′) symmetry in their global minimum structure. The uniqu...

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Detalles Bibliográficos
Autores principales:	Chen, Chen, Wang, Meng-hui, Feng, Lin-Yan, Zhao, Lian-Qing, Guo, Jin-Chang, Zhai, Hua-Jin, Cui, Zhong-hua, Pan, Sudip, Merino, Gabriel
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9278486/ https://www.ncbi.nlm.nih.gov/pubmed/35919428 http://dx.doi.org/10.1039/d2sc01761j

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