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Production of Gas Diffusion Layers with Tunable Characteristics

[Image: see text] Gas diffusion electrodes (GDEs) allow electrochemical reactions to occur at higher rates by enhancing the mass transport of gaseous reactants to the catalyst. These electrodes are made of two layers: the catalyst layer and the gas diffusion layer (GDL). The catalyst layer is freque...

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Autores principales: Philips, Matthew F., Gruter, Gert-Jan M., Koper, Marc T. M., Schouten, Klaas Jan P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9280951/
https://www.ncbi.nlm.nih.gov/pubmed/35847314
http://dx.doi.org/10.1021/acsomega.1c06977
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author Philips, Matthew F.
Gruter, Gert-Jan M.
Koper, Marc T. M.
Schouten, Klaas Jan P.
author_facet Philips, Matthew F.
Gruter, Gert-Jan M.
Koper, Marc T. M.
Schouten, Klaas Jan P.
author_sort Philips, Matthew F.
collection PubMed
description [Image: see text] Gas diffusion electrodes (GDEs) allow electrochemical reactions to occur at higher rates by enhancing the mass transport of gaseous reactants to the catalyst. These electrodes are made of two layers: the catalyst layer and the gas diffusion layer (GDL). The catalyst layer is frequently studied for gas diffusion electrodes, and the GDL is rarely a focus. Consequently, no studies investigate interaction effects that may be present between these two layers. To study such interactions, it must be possible to obtain GDLs with various characteristics. This study uses a design of experiments to understand how multiple factors in the production method for GDLs can be adjusted to tune the characteristics of the GDL. These GDLs are particularly intended for the electrochemical reduction of CO(2). The conductance through the GDL, surface conductivity, thickness, elasticity, hydrophobicity, and porosity are measured for the 26 synthesized electrodes, and the top influential production factors are identified for each characteristic.
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spelling pubmed-92809512022-07-15 Production of Gas Diffusion Layers with Tunable Characteristics Philips, Matthew F. Gruter, Gert-Jan M. Koper, Marc T. M. Schouten, Klaas Jan P. ACS Omega [Image: see text] Gas diffusion electrodes (GDEs) allow electrochemical reactions to occur at higher rates by enhancing the mass transport of gaseous reactants to the catalyst. These electrodes are made of two layers: the catalyst layer and the gas diffusion layer (GDL). The catalyst layer is frequently studied for gas diffusion electrodes, and the GDL is rarely a focus. Consequently, no studies investigate interaction effects that may be present between these two layers. To study such interactions, it must be possible to obtain GDLs with various characteristics. This study uses a design of experiments to understand how multiple factors in the production method for GDLs can be adjusted to tune the characteristics of the GDL. These GDLs are particularly intended for the electrochemical reduction of CO(2). The conductance through the GDL, surface conductivity, thickness, elasticity, hydrophobicity, and porosity are measured for the 26 synthesized electrodes, and the top influential production factors are identified for each characteristic. American Chemical Society 2022-06-27 /pmc/articles/PMC9280951/ /pubmed/35847314 http://dx.doi.org/10.1021/acsomega.1c06977 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Philips, Matthew F.
Gruter, Gert-Jan M.
Koper, Marc T. M.
Schouten, Klaas Jan P.
Production of Gas Diffusion Layers with Tunable Characteristics
title Production of Gas Diffusion Layers with Tunable Characteristics
title_full Production of Gas Diffusion Layers with Tunable Characteristics
title_fullStr Production of Gas Diffusion Layers with Tunable Characteristics
title_full_unstemmed Production of Gas Diffusion Layers with Tunable Characteristics
title_short Production of Gas Diffusion Layers with Tunable Characteristics
title_sort production of gas diffusion layers with tunable characteristics
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9280951/
https://www.ncbi.nlm.nih.gov/pubmed/35847314
http://dx.doi.org/10.1021/acsomega.1c06977
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