Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors

[Image: see text] Two new sulfur- and selenium-rich pentacyclic aromatic compounds were prepared by short chemical syntheses. The two donors readily formed charge transfer (CT) complexes upon reaction with antimony pentachloride or tris(4-bromophenyl)ammoniumyl hexachloroantimonate. The X-ray struct...

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Autores principales: Qin, Qian, Hebert, André J., Cruz, Ricardo L., Mague, Joel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9281308/
https://www.ncbi.nlm.nih.gov/pubmed/35847256
http://dx.doi.org/10.1021/acsomega.2c01549
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author Qin, Qian
Hebert, André J.
Cruz, Ricardo L.
Mague, Joel T.
author_facet Qin, Qian
Hebert, André J.
Cruz, Ricardo L.
Mague, Joel T.
author_sort Qin, Qian
collection PubMed
description [Image: see text] Two new sulfur- and selenium-rich pentacyclic aromatic compounds were prepared by short chemical syntheses. The two donors readily formed charge transfer (CT) complexes upon reaction with antimony pentachloride or tris(4-bromophenyl)ammoniumyl hexachloroantimonate. The X-ray structures of the heterocyclic donors and their CT complexes were determined. The donors flattened considerably upon CT complex formation.
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spelling pubmed-92813082022-07-15 Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors Qin, Qian Hebert, André J. Cruz, Ricardo L. Mague, Joel T. ACS Omega [Image: see text] Two new sulfur- and selenium-rich pentacyclic aromatic compounds were prepared by short chemical syntheses. The two donors readily formed charge transfer (CT) complexes upon reaction with antimony pentachloride or tris(4-bromophenyl)ammoniumyl hexachloroantimonate. The X-ray structures of the heterocyclic donors and their CT complexes were determined. The donors flattened considerably upon CT complex formation. American Chemical Society 2022-06-27 /pmc/articles/PMC9281308/ /pubmed/35847256 http://dx.doi.org/10.1021/acsomega.2c01549 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Qin, Qian
Hebert, André J.
Cruz, Ricardo L.
Mague, Joel T.
Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors
title Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors
title_full Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors
title_fullStr Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors
title_full_unstemmed Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors
title_short Charge Transfer Complexes of New Sulfur- and Selenium-Rich Aromatic Donors
title_sort charge transfer complexes of new sulfur- and selenium-rich aromatic donors
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9281308/
https://www.ncbi.nlm.nih.gov/pubmed/35847256
http://dx.doi.org/10.1021/acsomega.2c01549
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