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Competition Between C(α)‐S and C(α)‐C(β) Bond Cleavage in β‐Hydroxysulfoxides Cation Radicals Generated by Photoinduced Electron Transfer
A kinetic and product study of the 3‐cyano‐N‐methyl‐quinolinium photoinduced monoelectronic oxidation of a series of β‐hydroxysulfoxides has been carried out to investigate the competition between C(α)‐S and C(α)‐C(β) bond cleavage within the corresponding cation radicals. Laser flash photolysis exp...
Autores principales: | Lapi, Andrea, D'Alfonso, Claudio, Del Giacco, Tiziana, Lanzalunga, Osvaldo |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9290654/ https://www.ncbi.nlm.nih.gov/pubmed/33998681 http://dx.doi.org/10.1111/php.13455 |
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