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A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols

Selective oxidation of higher alcohols using heterogeneous catalysts is an important reaction in the synthesis of fine chemicals with added value. Though the process for primary alcohol oxidation is industrially established, there is still a lack of fundamental understanding considering the complexi...

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Autores principales: Najafishirtari, Sharif, Friedel Ortega, Klaus, Douthwaite, Mark, Pattisson, Samuel, Hutchings, Graham J., Bondue, Christoph J., Tschulik, Kristina, Waffel, Daniel, Peng, Baoxiang, Deitermann, Michel, Busser, G. Wilma, Muhler, Martin, Behrens, Malte
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292687/
https://www.ncbi.nlm.nih.gov/pubmed/34596294
http://dx.doi.org/10.1002/chem.202102868
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author Najafishirtari, Sharif
Friedel Ortega, Klaus
Douthwaite, Mark
Pattisson, Samuel
Hutchings, Graham J.
Bondue, Christoph J.
Tschulik, Kristina
Waffel, Daniel
Peng, Baoxiang
Deitermann, Michel
Busser, G. Wilma
Muhler, Martin
Behrens, Malte
author_facet Najafishirtari, Sharif
Friedel Ortega, Klaus
Douthwaite, Mark
Pattisson, Samuel
Hutchings, Graham J.
Bondue, Christoph J.
Tschulik, Kristina
Waffel, Daniel
Peng, Baoxiang
Deitermann, Michel
Busser, G. Wilma
Muhler, Martin
Behrens, Malte
author_sort Najafishirtari, Sharif
collection PubMed
description Selective oxidation of higher alcohols using heterogeneous catalysts is an important reaction in the synthesis of fine chemicals with added value. Though the process for primary alcohol oxidation is industrially established, there is still a lack of fundamental understanding considering the complexity of the catalysts and their dynamics under reaction conditions, especially when higher alcohols and liquid‐phase reaction media are involved. Additionally, new materials should be developed offering higher activity, selectivity, and stability. This can be achieved by unraveling the structure–performance correlations of these catalysts under reaction conditions. In this regard, researchers are encouraged to develop more advanced characterization techniques to address the complex interplay between the solid surface, the dissolved reactants, and the solvent. In this mini‐review, we report some of the most important approaches taken in the field and give a perspective on how to tackle the complex challenges for different approaches in alcohol oxidation while providing insight into the remaining challenges.
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spelling pubmed-92926872022-07-20 A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols Najafishirtari, Sharif Friedel Ortega, Klaus Douthwaite, Mark Pattisson, Samuel Hutchings, Graham J. Bondue, Christoph J. Tschulik, Kristina Waffel, Daniel Peng, Baoxiang Deitermann, Michel Busser, G. Wilma Muhler, Martin Behrens, Malte Chemistry Minireviews Selective oxidation of higher alcohols using heterogeneous catalysts is an important reaction in the synthesis of fine chemicals with added value. Though the process for primary alcohol oxidation is industrially established, there is still a lack of fundamental understanding considering the complexity of the catalysts and their dynamics under reaction conditions, especially when higher alcohols and liquid‐phase reaction media are involved. Additionally, new materials should be developed offering higher activity, selectivity, and stability. This can be achieved by unraveling the structure–performance correlations of these catalysts under reaction conditions. In this regard, researchers are encouraged to develop more advanced characterization techniques to address the complex interplay between the solid surface, the dissolved reactants, and the solvent. In this mini‐review, we report some of the most important approaches taken in the field and give a perspective on how to tackle the complex challenges for different approaches in alcohol oxidation while providing insight into the remaining challenges. John Wiley and Sons Inc. 2021-10-13 2021-12-06 /pmc/articles/PMC9292687/ /pubmed/34596294 http://dx.doi.org/10.1002/chem.202102868 Text en © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ (https://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Minireviews
Najafishirtari, Sharif
Friedel Ortega, Klaus
Douthwaite, Mark
Pattisson, Samuel
Hutchings, Graham J.
Bondue, Christoph J.
Tschulik, Kristina
Waffel, Daniel
Peng, Baoxiang
Deitermann, Michel
Busser, G. Wilma
Muhler, Martin
Behrens, Malte
A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols
title A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols
title_full A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols
title_fullStr A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols
title_full_unstemmed A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols
title_short A Perspective on Heterogeneous Catalysts for the Selective Oxidation of Alcohols
title_sort perspective on heterogeneous catalysts for the selective oxidation of alcohols
topic Minireviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292687/
https://www.ncbi.nlm.nih.gov/pubmed/34596294
http://dx.doi.org/10.1002/chem.202102868
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