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Origin of the Rate Acceleration in the C−C Reductive Elimination from Pt(IV)‐complex in a [Ga(4)L(6)](12−) Supramolecular Metallocage
The reductive elimination on [(Me(3)P)(2)Pt(MeOH)(CH(3))(3)](+), 2P, complex performed in MeOH solution and inside a [Ga(4)L(6)](12−) metallocage are computationally analysed by mean of QM and MD simulations and compared with the mechanism of gold parent systems previously reported [Et(3)PAu(MeOH)(C...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9293218/ https://www.ncbi.nlm.nih.gov/pubmed/34545974 http://dx.doi.org/10.1002/chem.202102250 |