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Molybdenum‐Mediated N(2)‐Splitting and Functionalization in the Presence of a Coordinated Alkyne
A new [PCCP]‐coordinated molybdenum platform comprising a coordinated alkyne was employed for the cleavage of molecular dinitrogen. The coordinated η (2)‐alkyne was left unaffected during this reduction. DFT calculations suggest that the reaction proceeds via an initially generated terminal N(2)‐com...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9297880/ https://www.ncbi.nlm.nih.gov/pubmed/34618390 http://dx.doi.org/10.1002/anie.202111325 |