Cargando…
THF‐solvated Heavy Alkali Metal Benzyl Compounds (Na, Rb, Cs): Defined Deprotonation Reagents for Alkali Metal Mediation Chemistry
The incorporation of heavy alkali metals into substrates is both challenging and essential for many reactions. Here, we report the formation of THF‐solvated alkali metal benzyl compounds [PhCH(2)M ⋅ (thf)(n)] (M=Na, Rb, Cs). The synthesis was carried out by deprotonation of toluene with the bimetall...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298144/ https://www.ncbi.nlm.nih.gov/pubmed/34633717 http://dx.doi.org/10.1002/chem.202103430 |