Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses

α‐Diimine ligands have significantly shaped the coordination chemistry of most transition metal complexes. Among them, bis(imino)acenaphthene ligands (BIANs) have recently been matured to great versatility and applicability to catalytic reactions. Besides variations of the ligand periphery, the grea...

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Detalles Bibliográficos
Autores principales: Bernauer, Josef, Pölker, Jennifer, Jacobi von Wangelin, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Minireviews
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298226/
https://www.ncbi.nlm.nih.gov/pubmed/35875682
http://dx.doi.org/10.1002/cctc.202101182
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author Bernauer, Josef
Pölker, Jennifer
Jacobi von Wangelin, Axel
author_facet Bernauer, Josef
Pölker, Jennifer
Jacobi von Wangelin, Axel
author_sort Bernauer, Josef
collection PubMed
description α‐Diimine ligands have significantly shaped the coordination chemistry of most transition metal complexes. Among them, bis(imino)acenaphthene ligands (BIANs) have recently been matured to great versatility and applicability to catalytic reactions. Besides variations of the ligand periphery, the great versatility of BIAN ligands resides within their ability to undergo facile electronic manipulations. This review highlights key aspects of BIAN ligands in metal complexes and summarizes recent contributions of metal‐BIAN catalysts to syntheses of small and functionalized organic molecules.
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spelling pubmed-92982262022-07-21 Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses Bernauer, Josef Pölker, Jennifer Jacobi von Wangelin, Axel ChemCatChem Minireviews α‐Diimine ligands have significantly shaped the coordination chemistry of most transition metal complexes. Among them, bis(imino)acenaphthene ligands (BIANs) have recently been matured to great versatility and applicability to catalytic reactions. Besides variations of the ligand periphery, the great versatility of BIAN ligands resides within their ability to undergo facile electronic manipulations. This review highlights key aspects of BIAN ligands in metal complexes and summarizes recent contributions of metal‐BIAN catalysts to syntheses of small and functionalized organic molecules. John Wiley and Sons Inc. 2021-10-22 2022-01-10 /pmc/articles/PMC9298226/ /pubmed/35875682 http://dx.doi.org/10.1002/cctc.202101182 Text en © 2021 The Authors. ChemCatChem published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Minireviews
Bernauer, Josef
Pölker, Jennifer
Jacobi von Wangelin, Axel
Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses
title Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses
title_full Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses
title_fullStr Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses
title_full_unstemmed Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses
title_short Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses
title_sort redox‐active bian‐based diimine ligands in metal‐catalyzed small molecule syntheses
topic Minireviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9298226/
https://www.ncbi.nlm.nih.gov/pubmed/35875682
http://dx.doi.org/10.1002/cctc.202101182
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AT polkerjennifer redoxactivebianbaseddiimineligandsinmetalcatalyzedsmallmoleculesyntheses
AT jacobivonwangelinaxel redoxactivebianbaseddiimineligandsinmetalcatalyzedsmallmoleculesyntheses

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