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Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes

Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl, NHC=N‐heterocyclic carbene=pyrid‐2‐ylimidazol‐2‐ylidene (Py−Im), thiophen‐2‐ylimidazol‐2‐ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores of SBA‐15 with average pore diameters of 5.0...

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Detalles Bibliográficos
Autores principales:	Panyam, Pradeep K. R., Atwi, Boshra, Ziegler, Felix, Frey, Wolfgang, Nowakowski, Michal, Bauer, Matthias, Buchmeiser, Michael R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299010/ https://www.ncbi.nlm.nih.gov/pubmed/34672398 http://dx.doi.org/10.1002/chem.202103099

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