Merging of a Perylene Moiety Enables a Ru(II) Photosensitizer with Long‐Lived Excited States and the Efficient Production of Singlet Oxygen

Multichromophoric systems based on a Ru(II) polypyridine moiety containing an additional organic chromophore are of increasing interest with respect to different light‐driven applications. Here, we present the synthesis and detailed characterization of a novel Ru(II) photosensitizer, namely [(tbbpy)(2)Ru((2‐(perylen‐3‐yl)‐1H‐imidazo[4,5‐f][1,10]‐phenanthrolline))](PF(6))(2) RuipPer, that includes a merged perylene dye in the back of the ip ligand. This complex features two emissive excited states as well as a long‐lived (8 μs) dark state in acetonitrile solution. Compared to prototype [(bpy)(3)Ru](2+)‐like complexes, a strongly altered absorption (ϵ=50.3×10(3) M(−1) cm(−1) at 467 nm) and emission behavior caused by the introduction of the perylene unit is found. A combination of spectro‐electrochemistry and time‐resolved spectroscopy was used to elucidate the nature of the excited states. Finally, this photosensitizer was successfully used for the efficient formation of reactive singlet oxygen.