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Size‐Induced Inversion of Selectivity in the Acylation of 1,2‐Diols
Relative rates for the Lewis base‐catalyzed acylation of aryl‐substituted 1,2‐diols with anhydrides differing in size have been determined by turnover‐limited competition experiments and absolute kinetics measurements. Depending on the structure of the anhydride reagent, the secondary hydroxyl group...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299827/ https://www.ncbi.nlm.nih.gov/pubmed/34693585 http://dx.doi.org/10.1002/chem.202101905 |