Cargando…

Crossed Regio‐ and Enantioselective Iron‐Catalyzed [4+2]‐Cycloadditions of Unactivated Dienes

The cyclohexene motif is ubiquitous in nature and specialty chemicals. A straightforward selective access to chiral cyclohexenes from unactivated dienes and dienophiles is not feasible by classical Diels–Alder reaction and constitutes an unsolved synthetic challenge. We report a mild and enantiosele...

Descripción completa

Detalles Bibliográficos
Autores principales: Braconi, Elena, Cramer, Nicolai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9299977/
https://www.ncbi.nlm.nih.gov/pubmed/34708502
http://dx.doi.org/10.1002/anie.202112148