Two Faces of the Bi−O Bond: Photochemically and Thermally Induced Dehydrocoupling for Si−O Bond Formation

The diorgano(bismuth)alcoholate [Bi((C(6)H(4)CH(2))(2)S)OPh] (1‐OPh) has been synthesized and fully characterized. Stoichiometric reactions, UV/Vis spectroscopy, and (TD‐)DFT calculations suggest its susceptibility to homolytic and heterolytic Bi−O bond cleavage under given reaction conditions. Usin...

Descripción completa

Detalles Bibliográficos
Autores principales: Ramler, Jacqueline, Schwarzmann, Johannes, Stoy, Andreas, Lichtenberg, Crispin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300068/
https://www.ncbi.nlm.nih.gov/pubmed/35873275
http://dx.doi.org/10.1002/ejic.202100934

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300068/
https://www.ncbi.nlm.nih.gov/pubmed/35873275
http://dx.doi.org/10.1002/ejic.202100934

Ejemplares similares