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Two Faces of the Bi−O Bond: Photochemically and Thermally Induced Dehydrocoupling for Si−O Bond Formation

The diorgano(bismuth)alcoholate [Bi((C(6)H(4)CH(2))(2)S)OPh] (1‐OPh) has been synthesized and fully characterized. Stoichiometric reactions, UV/Vis spectroscopy, and (TD‐)DFT calculations suggest its susceptibility to homolytic and heterolytic Bi−O bond cleavage under given reaction conditions. Usin...

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Detalles Bibliográficos
Autores principales:	Ramler, Jacqueline, Schwarzmann, Johannes, Stoy, Andreas, Lichtenberg, Crispin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300068/ https://www.ncbi.nlm.nih.gov/pubmed/35873275 http://dx.doi.org/10.1002/ejic.202100934

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