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Missing Member in the M (II) M (III)Si(4)N(7) Compound Class: Carbothermal Reduction and Nitridation Synthesis Reveal Substitution of Nitrogen by Carbon and Oxygen in CaLu[Si(4)N(7–2x )C( x )O( x )]:Eu(2+)/Ce(3+) (x≈0.3)
The nitridosilicate CaLu[Si(4)N(7–2x )C( x )O( x )] (x≈0.3) was synthesized by carbothermal reduction and nitridation starting from CaH(2), Lu(2)O(3), graphite and amorphous Si(3)N(4) at 1550 °C in a radiofrequency furnace. CaLu[Si(4)N(7–2x )C( x )O( x )] (x≈0.3) crystallizes isotypically to many pr...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300086/ https://www.ncbi.nlm.nih.gov/pubmed/34846075 http://dx.doi.org/10.1002/chem.202104007 |