Site‐Specific Reduction‐Induced Hydrogenation of a Helical Bilayer Nanographene with K and Rb Metals: Electron Multiaddition and Selective Rb(+) Complexation

The chemical reduction of π‐conjugated bilayer nanographene 1 (C(138)H(120)) with K and Rb in the presence of 18‐crown‐6 affords [K(+)(18‐crown‐6)(THF)(2)][{K(+)(18‐crown‐6)}(2)(THF)(0.5)][C(138)H(122) (3−)] (2) and [Rb(+)(18‐crown‐6)(2)][{Rb(+)(18‐crown‐6)}(2)(C(138)H(122) (3−))] (3). Whereas K(+)...

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Detalles Bibliográficos
Autores principales: Zhou, Zheng, Fernández‐García, Jesús M., Zhu, Yikun, Evans, Paul J., Rodríguez, Rafael, Crassous, Jeanne, Wei, Zheng, Fernández, Israel, Petrukhina, Marina A., Martín, Nazario
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300088/
https://www.ncbi.nlm.nih.gov/pubmed/34875130
http://dx.doi.org/10.1002/anie.202115747

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