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Regioselective Magnesiation and Zincation Reactions of Aromatics and Heterocycles Triggered by Lewis Acids
Mixed TMP‐bases (TMP=2,2,6,6‐tetramethylpiperidyl), such as TMPMgCl ⋅ LiCl, TMP(2)Mg ⋅ 2LiCl, TMPZnCl ⋅ LiCl and TMP(2)Zn ⋅ 2LiCl, are outstanding reagents for the metalation of functionalized aromatics and heterocycles. In the presence of Lewis acids, such as BF(3) ⋅ OEt(2) or MgCl(2), the metalati...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9300163/ https://www.ncbi.nlm.nih.gov/pubmed/34704653 http://dx.doi.org/10.1002/chem.202103269 |