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XAS and EPR in Situ Observation of Ru(V) Oxo Intermediate in a Ru Water Oxidation Complex

In this study, we combine in situ spectroelectrochemistry coupled with electron paramagnetic resonance (EPR) and X‐ray absorption spectroscopies (XAS) to investigate a molecular Ru‐based water oxidation catalyst bearing a polypyridinic backbone [Ru(II)(OH(2))(Py(2)Metacn)](2+) . Although high valent...

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Detalles Bibliográficos
Autores principales: Levin, Natalia, Casadevall, Carla, Cutsail, George E., Lloret‐Fillol, Julio, DeBeer, Serena, Rüdiger, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302654/
https://www.ncbi.nlm.nih.gov/pubmed/35874044
http://dx.doi.org/10.1002/celc.202101271

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