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Supported σ‐Complexes of Li−C Bonds from Coordination of Monomeric Molecules of LiCH(3), LiCH(2)CH(3) and LiC(6)H(5) to Mo≣Mo Bonds
LiCH(3) and LiCH(2)CH(3) react with the complex [Mo(2)(H)(2)(μ‐Ad(Dipp2))(2)(thf)(2)] (1⋅thf) with coordination of two molecules of LiCH(2)R (R=H, CH(3)) and formation of complexes [Mo(2){μ‐HLi(thf)CH(2)R}(2)(Ad(Dipp2))(2)], 5⋅LiCH(3) and 5⋅LiCH(2)CH(3) , respectively (Ad(Dipp2)=HC(NDipp)(2); Dipp=2...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303556/ https://www.ncbi.nlm.nih.gov/pubmed/34913550 http://dx.doi.org/10.1002/anie.202116009 |