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Thermo‐Reversible Cellulose Micro Phase‐Separation in Mixtures of Methyltributylphosphonium Acetate and γ‐Valerolactone or DMSO

We have identified cellulose solvents, comprised of binary mixtures of molecular solvents and ionic liquids that rapidly dissolve cellulose to high concentration and show upper‐critical solution temperature (UCST)‐like thermodynamic behaviour ‐ upon cooling and micro phase‐separation to roughly sphe...

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Detalles Bibliográficos
Autores principales: Holding, Ashley J., Xia, Jingwen, Hummel, Michael, Zwiers, Harry, Leskinen, Matti, Rico del Cerro, Daniel, Hietala, Sami, Nieger, Martin, Kemell, Marianna, Helminen, Jussi K. J., Aseyev, Vladimir, Tenhu, Heikki, Kilpeläinen, Ilkka, King, Alistair W. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303658/
https://www.ncbi.nlm.nih.gov/pubmed/35130371
http://dx.doi.org/10.1002/cphc.202100635

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