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Thermo‐Reversible Cellulose Micro Phase‐Separation in Mixtures of Methyltributylphosphonium Acetate and γ‐Valerolactone or DMSO
We have identified cellulose solvents, comprised of binary mixtures of molecular solvents and ionic liquids that rapidly dissolve cellulose to high concentration and show upper‐critical solution temperature (UCST)‐like thermodynamic behaviour ‐ upon cooling and micro phase‐separation to roughly sphe...
Autores principales: | Holding, Ashley J., Xia, Jingwen, Hummel, Michael, Zwiers, Harry, Leskinen, Matti, Rico del Cerro, Daniel, Hietala, Sami, Nieger, Martin, Kemell, Marianna, Helminen, Jussi K. J., Aseyev, Vladimir, Tenhu, Heikki, Kilpeläinen, Ilkka, King, Alistair W. T. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303658/ https://www.ncbi.nlm.nih.gov/pubmed/35130371 http://dx.doi.org/10.1002/cphc.202100635 |
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