Mechanism of the Bifunctional Multiple Product Sesterterpene Synthase AcAS from Aspergillus calidoustus

The multiproduct chimeric sesterterpene synthase AcAS from Aspergillus calidoustus yielded spirocyclic calidoustene, which exhibits a novel skeleton, besides five known sesterterpenes. The complex cyclisation mechanism to all six compounds was investigated by isotopic labelling experiments in combin...

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Detalles Bibliográficos
Autores principales: Quan, Zhiyang, Hou, Anwei, Goldfuss, Bernd, Dickschat, Jeroen S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303889/
https://www.ncbi.nlm.nih.gov/pubmed/35072966
http://dx.doi.org/10.1002/anie.202117273

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303889/
https://www.ncbi.nlm.nih.gov/pubmed/35072966
http://dx.doi.org/10.1002/anie.202117273

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