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Single-crystal-to-single-crystal translation of a helical supramolecular polymer to a helical covalent polymer
Polymers possessing helical conformation in the solid state are in high demand. We report a helical peptide-polymer via the topochemical ene-azide cycloaddition (TEAC) polymerization. The molecules of the designed Gly-Phe–based dipeptide, decorated with ene and azide, assemble in its crystals as β-s...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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National Academy of Sciences
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303982/ https://www.ncbi.nlm.nih.gov/pubmed/35858342 http://dx.doi.org/10.1073/pnas.2205320119 |