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Origin of the different reactivity of the high‐valent coinage‐metal complexes [RCu( iii )Me(3)](−) and [RAg( iii )Me(3)](−) (R=allyl)
High‐valent tetraalkylcuprates(iii) and ‐argentates(iii) are key intermediates of copper‐ and silver‐mediated C−C coupling reactions. Here, we investigate the previously reported contrasting reactivity of [RM( iii )Me(3)](−) complexes (M=Cu, Ag and R=allyl) with energy‐dependent collision‐induced di...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9304237/ https://www.ncbi.nlm.nih.gov/pubmed/34773654 http://dx.doi.org/10.1002/chem.202103130 |