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Synthesis, Reactivity and Structural Properties of Trifluoromethylphosphoranides

Phosphoranides are interesting hypervalent species which serve as model compounds for intermediates or transition states in nucleophilic substitution reactions at trivalent phosphorus substrates. Herein, the syntheses and properties of stable trifluoromethylphosphoranide salts are reported. [K(18‐cr...

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Detalles Bibliográficos
Autores principales: Shyshkov, Oleg O., Kolomeitsev, Alexander A., Hoge, Berthold, Lork, Enno, Haupt, Axel, Keßler, Mira, Röschenthaler, Gerd‐Volker
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9305102/
https://www.ncbi.nlm.nih.gov/pubmed/35025112
http://dx.doi.org/10.1002/chem.202104308

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