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Exceptional Manganese(II) Stability and Manganese(II)/Zinc(II) Selectivity with Rigid Polydentate Ligands

While Mn(II) complexes meet increasing interest in biomedical applications, ligands are lacking that enable high Mn(II) complex stability and selectivity vs. Zn(II), the most relevant biological competitor. We report here two new bispidine derivatives, which provide rigid and large coordination cavi...

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Detalles Bibliográficos
Autores principales: Cieslik, Patrick, Comba, Peter, Dittmar, Benedikt, Ndiaye, Daouda, Tóth, Éva, Velmurugan, Gunasekaran, Wadepohl, Hubert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9305554/
https://www.ncbi.nlm.nih.gov/pubmed/34979049
http://dx.doi.org/10.1002/anie.202115580