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NHC Catalysis for Umpolung Pyridinium Alkylation via Deoxy‐Breslow Intermediates

Umpolung N‐heterocyclic carbene (NHC) catalysis of non‐aldehyde substrates offers new pathways for C−C bond formation, but has proven challenging to develop in terms of viable substrate classes. Here, we demonstrate that pyridinium ions can undergo NHC addition and subsequent intramolecular C−C bond...

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Detalles Bibliográficos
Autores principales:	Wu, Terence, Tatton, Matthew R., Greaney, Michael F.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306516/ https://www.ncbi.nlm.nih.gov/pubmed/35103381 http://dx.doi.org/10.1002/anie.202117524

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