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Mechanochemical Grignard Reactions with Gaseous CO(2) and Sodium Methyl Carbonate
A one‐pot, three‐step protocol for the preparation of Grignard reagents from organobromides in a ball mill and their subsequent reactions with gaseous carbon dioxide (CO(2)) or sodium methyl carbonate providing aryl and alkyl carboxylic acids in up to 82 % yield is reported. Noteworthy are the short...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306648/ https://www.ncbi.nlm.nih.gov/pubmed/34942056 http://dx.doi.org/10.1002/anie.202116514 |